Identification

Title

Analytical results from lightning discharge experiments focusing on interactions between nitrogen oxides and pyrite

Abstract

The dataset includes measurements of dissolved and gaseous nitrogen oxides (nitrite, nitrate, NO(g)) generated by lightning discharge in a glass container partially filled with water, as well as measurements of dissolves sulfate and iron liberated from pyrite that has interacted with the nitrogen oxides. The lightning discharge experiments were carried out with either anoxic gas mixture (5% or 20% CO2 and the rest N2) or modern air. Lightning has long been identified as a source of reactive nitrogen species to Earth's early biosphere. These experiments were therefore conducted in order to test how this reactive nitrogen would interact with minerals at the Earth's surface. The results reveal that lightning-generated nitrogen oxides could have contributed to a small degree to oxidative weathering.

Resource type

nonGeographicDataset

Resource locator

https://webapps.bgs.ac.uk/services/ngdc/accessions/index.html#item184999

name: Data

function: download

https://doi.org/10.5285/9d11f724-6abe-4b70-9471-dc298f8ff597

name: Digital Object Identifier (DOI)

function: information

Unique resource identifier

code

http://data.bgs.ac.uk/id/dataHolding/13608240

codeSpace

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

geoscientificInformation

Keywords

Keyword set

keyword value

originating controlled vocabulary

title

GEMET - INSPIRE themes, version 1.0

reference date

date type

publication

effective date

2008-06-01

Keyword set

keyword value

Nitrogen oxides

NGDC Deposited Data

Archaean

Lightning

originating controlled vocabulary

title

BGS Thesaurus of Geosciences

reference date

date type

revision

effective date

2022

Keyword set

keyword value

Keyword set

keyword value

NERC_DDC

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

2022-08-01

End position

2024-03-01

Dataset reference date

date type

creation

effective date

2024-05-20

Frequency of update

notApplicable

Quality and validity

Lineage

The experimental setup was similar to that of Barth et al. (2023, Nature Geoscience). Pyrite was added to the reaction flask, along with 21ml of deoxygenated DI-water. Nitrite, nitrate and nitric oxide gas, as well as sulfate and iron were measured over time by extracting 3ml of liquid every 6 minutes with a syringe through a septum. The analyses were conduced with an ion chromatograph for nitrite, nitrate and sulfate. Iron was measured by spectrophotometry. Nitric oxide gas was measured with an quadrupole mass spectrometer. Analytical details are described in Long et al. (in review). The aqueous data were corrected for the volume change that occurred as fluid was extracted. All experiments were carried out in triplicates. Blank experiments were conducted where the spark generator was turned off.

Conformity

Conformity report

specification

title

INSPIRE Implementing rules laying down technical arrangements for the interoperability and harmonisation of Geology

reference date

date type

publication

effective date

2011

degree

false

explanation

See the referenced specification

Conformity report

specification

title

Commission Regulation (EU) No 1089/2010 of 23 November 2010 implementing Directive 2007/2/EC of the European Parliament and of the Council as regards interoperability of spatial data sets and services

reference date

date type

publication

effective date

2010-12-08

degree

false

explanation

See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF

Data format

name of format

MS Excel

version of format

Constraints related to access and use

Constraint set

Limitations on public access

Constraint set

Limitations on public access

The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.

pointOfContact

Metadata on metadata

Metadata point of contact

organisation name

British Geological Survey

full postal address

Environmental Science Centre,Keyworth

NOTTINGHAM

NG12 5GG

United Kingdom

telephone number

+44 115 936 3100

email address

enquiries@bgs.ac.uk

responsible party role

pointOfContact

Metadata date

2025-03-26

Metadata language

eng